Open-Chain Tetrapyrrole Spectra Database

OCTP164b

PhotochemCAD ID	OCTP164b

Absorption Spectrum

Absorption Wavelength	634
Absorption Epsilon	62500
Absorption Coefficient	62500 at 634 nm
Solvent	xylene
Reference	(Allik, 1994)
Spectrum Data	Download File

Fluorescence Spectrum

Solvent	xylene
Reference	(Allik, 1994)
Quantum Yield	0.37
Spectrum Data	Download File

"Absorption and fluorescence spectra of open-chain tetrapyrrole pigments-bilirubins, biliverdins, phycobilins, and synthetic analogues,"
Taniguchi, M.; Lindsey, J. S. J. Photochem. Photobiol. 2023, 55, 100585.

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[Braslavsky, 1991]	S.E. Braslavsky, D. Schneider, K. Heihoff, S. Nonell, P.F. Aramendia, K. Schaffner, Phytochrome models. 11. Photophysics and photochemistry of phycocyanobilin dimethyl ester, J. Am. Chem. Soc. 113 (1991) 7322–7334. https://doi.org/10.1021/ja00019a033
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[Chen, 1995a]	Q.-Q. Chen, H. Falk, On the chemistry of pyrrole pigments, XCIII: 1,2-bis-(dipyrrinon-9-ylidene)-ethane – a novel b-homoverdin chromophore, Monatsh. Chem. 126 (1995) 1097–1107. https://doi.org/10.1007/BF00811380
[Chen, 1995b]	Q.Q. Chen, H. Falk, On the chemistry of pyrrole pigments, XCIV: 1-(Dipyrrinon-9-yl)-3-(dipyrrinon-9-ylidene)-1-propene – a novel b-vinylogous verdin chromophore, Monatsh. Chem. 126 (1995) 1233–1244. https://doi.org/10.1007/BF00824302
[Chen, 1995c]	Q.-Q. Chen, H. Falk, On the chemistry of pyrrole pigments, XCV: 1,4-bis-(dipyrrinone-9-ylidene)-butene-2 – A novel b-homo-verdin chromophore, Monatsh. Chem. 126 (1995) 1323–1329. https://doi.org/10.1007/BF00807061
[Chen, 1999]	Q. Chen, M.T. Huggins, D.A. Lightner, W. Norona, A.F. McDonagh, Synthesis of a 10-oxo-bilirubin: Effects of the oxo group on conformation, transhepatic transport, and glucuronidation, J. Am. Chem. Soc. 121 (1999) 9253–9264. https://doi.org/10.1021/ja991814m
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[Edinger, 1984a]	J. Edinger, H. Falk, N. Müller, Zur chemie der pyrrolpigmente, 54. mitt.: Phytochrommodellstudien: Ein 2,3-dihydrobilatrien-abc-3-cholesterylderivat, Monatsh. Chem. 115 (1984) 837–852. https://doi.org/10.1007/BF01120979
[Edinger, 1984b]	J. Edinger, H. Falk, W. Jungwirth, N. Müller, U. Zrunek, Zur chemie der pyrrolpigmente, 56. mitt.: Phytochrommodellstudien: Die induzierten und natürlichen chiroptischen eigenschaften von bilatrienen-abc und 2,3-dihydrobilatrienen-abc, Monatsh. Chem. 115 (1984) 1081–1099. https://doi.org/10.1007/BF00798775
[Eivazi, 1977]	F. Eivazi, M.F. Hudson, K.M. Smith, Bile pigment studies III. Controlled oxidative degradation of 1,19(21,24)-bilindiones (bilitrienes), Tetrahedron 33 (1977) 2959–2964. https://doi.org/10.1016/0040-4020(77)88030-7
[Falk, 1978]	H. Falk, K. Grubmayr, E. Haslinger, T. Schlederer, K. Thirring, Beiträge zur chemie der pyrrolpigmente, 25. mitt.: Die diastereomeren (geometrisch isomeren) biliverdindimethylester – Struktur, konfiguration und konformation, Monatsh. Chem. 109 (1978) 1451–1473. https://doi.org/10.1007/BF00906057
[Falk, 1979a]	H. Falk, K. Thirring, Beiträge zur Chemie der pyrrolpigmente, XXXIII. Darstellung, struktur und eigenschaften von isomeren N-methyl-bilatrienen-abc (N-methyl-etiobiliverdine-IV-γ), Z. Naturforsch. B 34 (1979) 1448–1453. https://doi.org/10.1515/znb-1979-1020
[Falk, 1979b]	H. Falk, T. Schlederer, Beiträge zur Chemie der Pyrrolpigmente, XXX. Struktur und eigenschaften der laktimform eines bilatriens-abc (ätiobiliverdin-IV-γ), Liebigs Ann. Chem. 1979 (1979) 1560–1570. https://doi.org/10.1002/jlac.197919791015
[Falk, 1979c]	H. Falk, K. Thirring, Beiträge zur chemie der pyrrolpigmente, XXXIV. Über die konfiguration und konformation von diastereomeren N-methyl-O-methyl-bilatrienen-abc, Z. Naturforsch. B 34 (1979) 1600–1605. https://doi.org/10.1515/znb-1979-1123
[Falk, 1980a]	H. Falk, N. Müller, T. Schlederer, Beiträge zur chemie der pyrrolpigmente, 35. mitt.: Eine regioselektive, reversible addition an bilatriene-abc, Monatsh. Chem. 111 (1980) 159–175. https://doi.org/10.1007/BF00938725
[Falk, 1980b]	H. Falk, K. Thirring, Beiträge zur chemie der pyrrolpigmente, XXXVI. Zur anaeroben photochemie von 21.24-dimethy-aetiobiIiverdin-IV-γ, Z. Naturforsch. B 35 (1980) 376–380. https://doi.org/10.1515/znb-1980-0322
[Falk, 1981a]	H. Falk, T. Schlederer, P. Wolschann, Beiträge zur chemie der pyrrolpigmente, 38. mitt.: Zur assoziation von gallenpigmenten, Monatsh. Chem. 112 (1981) 199–207. https://doi.org/10.1007/BF00911086
[Falk, 1981b]	H. Falk, K. Thirring, Beiträge zur chemie der pyrrolpigmente-XXXVII: Überbrückte gallenpiqmente: N21-N24-methylen-aetiobiliverdin- IV-γ und N21-N24-methylen-aetiobilirubin-IV-γ, Tetrahedron 37 (1981) 761–766. https://doi.org/10.1016/S0040-4020(01)97694-X
[Falk, 1983]	H. Falk, U. Zrunek, Beiträge zur chemie der pyrrolpigmente, 50. mitt.: Phytochrommodellstudien: Das laktam – Laktimgleichgewicht des pyrrolidinonfragmentes von 2,3-dihydrobilatrienen-abc – Protonierungsgleichgewichte, Monatsh. Chem. 114 (1983) 983–998. https://doi.org/10.1007/BF00799958
[Falk, 1984a]	H. Falk, U. Zrunek, Beiträge zur chemie der pyrrolpigmente, 52. mitt.: Phytochrommodellstudien: Eine reversible addition an Δ-4 von 2,3-dihydrobilatrienen-abc, Monatsh. Chem. 115 (1984) 101–111. https://doi.org/10.1007/BF00798426
[Falk, 1984b]	H. Falk, P. Wolschann, U. Zrunek, Beiträge zur chemie der pyrrolpigmente, 53. mitt.: Phytochrommodellstudien: Das säure-basen-gleichgewicht diastereomerer 2,3-dihydrobilatriene-abc, Monatsh. Chem. 115 (1984) 243–249. https://doi.org/10.1007/BF00798415
[Falk, 1985a]	H. Falk, H. Gsaller, E. Hubauer, N. Müller, Beiträge zur chemie der pyrrolpigmente, 61. mitt.: Phytochrommodellstudien – Absorptionsspektren und strukturelle aspekte von 2,3-dihydrobilatrienen-abc aus der sicht eines semiempirischen quantenchemischen verfahrens (PPP-SCF-LCAO-MO-CI), Monatsh. Chem. 116 (1985) 939–959. https://doi.org/10.1007/BF00809188
[Falk, 1985b]	H. Falk, N. Müller, S. Wansch, Zur chemie der pyrrolpigmente, 63. mitt.: Phytochrommodellstudien: Das system 2,3-dihydrobilatrien – Hexamethylphosphorsäuretriamid als modell für gestreckte chromophore, Monatsh. Chem. 116 (1985) 1087–1097. https://doi.org/10.1007/BF00809199
[Falk, 1985c]	H. Falk, H. Flödl, Beiträge zur chemie der pyrrolpigmente, 64. mitt.: 2,3,7,8,12,13,17,18,22,23-Decamethyl-1,24,25,29-tetrahydro-27H-pentapyrrin-1,24-dion, der erste vertreter linearer pentapyrrole: Darstellung und struktur im gelösten zustand, Monatsh. Chem. 116 (1985) 1177–1187. https://doi.org/10.1007/BF00811251
[Falk, 1986a]	H. Falk, H. Flödl, Beiträge zur chemie der pyrrolpigmente, 65. mitt.: 2,3,7,8,12,13,17,18,22,23-Decamethyl-1,24,25,29-tetrahydro-27H-pentapyrrin-1,24-dion, der erste vertreter linearer pentapyrrole: Eigenschaften und reaktionsweisen, Monatsh. Chem. 117 (1986) 57–67. https://doi.org/10.1007/BF00809173
[Falk, 1986b]	H. Falk, A. Hinterberger, Beiträge zur chemie der pyrrolpigmente, 67. mitt.: Bilatriene-abc und 2,3-dihydrobilatriene-abc in micellaren systemen, Monatsh. Chem. 117 (1986) 1081–1090. https://doi.org/10.1007/BF00811278
[Falk, 1988a]	H. Falk, W. Medinger, N. Müller, Beiträge zur chemie der pyrrolpigmente, 75. mitt. Phytochrom-modell-studien: Stereochemische untersuchungen an einem zwischen den pyrrolischen ringen A und C peptidartig überbrückten 2,3-dihydrobilatrien-abc, Monatsh. Chem. 119 (1988) 113–126. https://doi.org/10.1007/BF00810093
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